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Arrays of Stereogenic Centers: The Aisa Synthesis of Guaipyridine

Chemexpress March 25, 2024 0 Comments

Alois Fürstner of the Max-Planck-Institut für Kohlenforschung set the relative and absolute configuration of 3 by the Ni-mediated addition of the enol ether 2 to the aldehyde 1 (J. Am.…

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Delicato Dipartimento di Scienze e Tecnologie Biologiche, ` Chimiche, Farmaceutiche, Universita di

Chemexpress March 24, 2024 0 Comments

Delicato Dipartimento di Scienze e Tecnologie Biologiche, ` Chimiche, Farmaceutiche, Universita di Palermo, Parco Orleans II, Ed. 17, 1690128 Palermo, Italy e mail: [email protected] R. Indelicato S. Barreca ` Dipartimento…

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Y by elevated apoptosis within a Rho/Rhoassociated kinase (ROCK)dependent

Chemexpress March 24, 2024 0 Comments

Y by improved apoptosis within a Rho/Rhoassociated kinase (ROCK)dependent mechanism. Moreover, LPA inhibited the neuronal differentiation of iPSCs. Lastly, LPA induced neurite retraction of NS/ PCderived early neurons via Rho/ROCK,…

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C-H Functionalization: The Davies/Sorensen Synthesis of Aflatoxin B2

Chemexpress March 24, 2024 0 Comments

Shouyun Yu of Nanjing University devised a protocol for the distal dehydrogenation of the acyloxyamide 1 to the alkene 2 (Org. Lett. 2021, 23, 6931. DOI: 10.1021/acs.orglett.1c02509). Armido Studer of…

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Carbon-Carbon Bond Formation: The Fürstner Synthesis of Scabrolide A

Chemexpress March 24, 2024 0 Comments

Yasuharu Yoshimi of the University of Fukui devised a photocatalyst that efficiently promoted the coupling of the acid 1 with acrylonitrile 2, to give, with the net addition of two…

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N-Heterocycle Construction by Alkene Metathesis

Chemexpress March 24, 2024 0 Comments

The first N-heterocycles prepared by alkene metathesis were simple five- and six-membered ring amides. Ring-closing metathesis of free amines is much more difficult. The diene 1, for instance, gave only…

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Reactions of Alkenes: The Yang Synthesis of Bisdihydrotuberostemonine D

Chemexpress March 24, 2024 0 Comments

Qiang Liu and Yibiao Li of Wuyi University developed a simple protocol for exchanging deuterium into the alkene 1, leading to 2 (Org. Lett. 2021, 23, 7412. DOI: 10.1021/acs.orglett.1c02600). Joseph…

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Functional Group Interconversion: The Minehan Synthesis of Jambolanin C

Chemexpress March 24, 2024 0 Comments

Julian G. 61881-19-4 web West of Rice University used a vitamin B12-based catalyst to prepare the terminal alkene 2 by the elimination of the primary bromide 1 (Chem. PMID:31085260 Sci.…

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Alkaloid Synthesis: Aristoquinoline (Reber), Hinckdentine A (Su/Hong), Madangamine E (Hamlin/Dixon), Normacusine B (Xue/Qin), Daphenylline (Lu), Arboridine (Ma)

Chemexpress March 24, 2024 0 Comments

Aristoquinoline (2), isolated from the leaves of the Maqui tree Aristotelia chilensis, was found to be a nicotinic acetylcholine receptor antagonist. BuyMethyl 6-aminopicolinate Buy130473-38-0 Keith P. Reber of Towson University…

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Diels-Alder Cycloaddition: Pepluanol A (Gaich), Trichoderone A (Nay), Davasinol (Ding), Nahuoic Acid A (Alvarez/de Lera), Chloropestolide B (Suzuki), Catharanthine (Dixon)

Chemexpress March 24, 2024 0 Comments

Pepluanol A (3) was isolated from the European milkweed Euphorbia peplus. 957476-07-2 uses BuyLumisterol 3 (>90%) Tanja Gaich of the University of Konstanz devised a route to 3 based on…

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