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Enantioselective Synthesis of Alcohols and Amines: The Yang Synthesis of Colchicine

Chemexpress March 21, 2024 0 Comments

Guosheng Liu of the Shanghai Institute of Organic Chemistry devised the enantioselective Pd-catalyzed diacetoxylation of the alkene 1 to the bis-acetate 2 (Nature Catal. 2021, 4, 172. DOI: 10.1038/s41929-021-00574-5). Bingxian…

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Diastereoselective and Enantioselective Construction of Cyclic Ethers

Chemexpress March 21, 2024 0 Comments

Because the stereocontrolled construction of cyclic ethers has been difficult and expensive, the use of cyclic ethers as pharmaceuticals has not been fully explored. 1,2,3,4-Tetrahydrobenzoquinoline Chemical name With the development…

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Substituted Benzenes: The Yang/Zhang Synthesis of Cephanolide B

Chemexpress March 21, 2024 0 Comments

Duen-Ren Hou of the National Central University devised a simple protocol for the direct acetoxylation of the substituted benzene 1, leading to the aryl acetate 2 (Org. Lett. 2021, 23,…

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Organometallic C-C Ring Construction: The Nishikawa/Morimoto Synthesis of Toxicodenane A

Chemexpress March 21, 2024 0 Comments

Xihe Bi of Northeast Normal University showed that the diazo alkane generated in situ from the sulfonylhydrazide 2 could with a silver catalyst be added to the alkene 1, to…

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Oxidation: The Cossy/Amara Route to Artemisinin

Chemexpress March 21, 2024 0 Comments

Chen Xu of the Southern University of Science and Technology and Zheng Huang of the Shanghai Institute of Organic Chemistry effected the acceptorless photochemical dehydrogenation of the sulfide 1 to…

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Enantioselective Synthesis of Alcohols and Amines: The Yajima Synthesis of 1,3,5-Bisabolatrien-7-ol

Chemexpress March 21, 2024 0 Comments

Aaron Aponick of the University of Florida achieved high ee in the cyclization of the allylic alcohol 1 to the lactone 2 (Angew. Chem. Int. Ed. 2021, 60, 22224. DOI:…

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C-N Ring Construction: The del Pozo Synthesis of Myrtine

Chemexpress March 21, 2024 0 Comments

Tom G. Driver of the University of Illinois at Chicago developed oxidative conditions for the preparation of the aziridine 3 by the addition of the aniline 2 to the alkene…

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N was performed by the identical men and women as inside the preceding

Chemexpress March 20, 2024 0 Comments

N was performed by the exact same people as within the preceding study (Hermann et al., 2012). Feasible elements incorporate the use of a rather higher dose of radiation in…

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Ret C, Dorel C, Hooreman M, Lejeune P (1998) Isolation of an

Chemexpress March 20, 2024 0 Comments

Ret C, Dorel C, Hooreman M, Lejeune P (1998) Isolation of an Escherichia coli K12 mutant strain able to type biofilms on inert surfaces: Involvement of a brand new ompR…

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C-O Ring Construction: The Makabe Synthesis of Muconin

Chemexpress March 20, 2024 0 Comments

Yu-Fei Ao and Hui Chen of the Institute of Chemistry, Chinese Academy of Sciences devised a mutant amidase that hydrolyzed the prochiral dihydrofuran bis amide 1 to the monoacid 2…

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  • 48 decrease than those perfused with BAY 412272 alone (11.15 0.91 vs. 17.76 1.87 fmol/mg tissue
  • Table 1, entry 4; Table 2, entry 1). Inside the presence of catalase (Table 2, entry
  • As then obtained by the leastsquare curve fitting. Next, the amount

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C experiments to mimic diagenesis at burial temperature. The outcomes highlighted

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Hed an in vitro assay in which intestinal epithelial cells were

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48 decrease than those perfused with BAY 412272 alone (11.15 0.91 vs. 17.76 1.87 fmol/mg tissue

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Table 1, entry 4; Table 2, entry 1). Inside the presence of catalase (Table 2, entry

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