One of the most powerful of alkene transformations is enantioselectiveepoxidation. Tsutomu Katsuki of Kyushu University has developed (Angew. Chem. Int. 2,5-Dimethoxy-4-formylphenylboronic acid Order Ed. 2007, 46, 4559.DOI: 10.1002/anie.200700949)a Ti catalyst…
As N. Azido-PEG8-acid Purity Selvakumar of Dr. Reddy’s Laboratories, Ltd., Hyderabad approached (Tetrahedron Lett. 2007, 48, 2021.DOI: 10.1016/j.tetlet.2007.01.053)the synthesis of phaseolinic acid (6), there was some concern about the projected…
A classic example of C-H functionalization is the familiarNBSbromination of a benzylic site. Recent updates of this approach allow for direct alkoxylation(J. Am. Chem. Soc. 2008, 130, 7824DOI: 10.1021/ja8031218)and net…
Rity in tuberculosis sufferers . In addition, the presence of V2+ T cells in the BALF in this study confirmed that alveolar macrophages infected with M. tuberculosis can grow to…
Ed sequentially in 50 , 60 , 70 , 80 , 90 , and 100 ethanol for 30 min each after which dried in 100 hexamethyldisilazane (HMDS). The dried samples…
Secondary alcohols can be prepared in high enantiomeric excess by catalytic hydrogenation of ketones. Zhaoguo Zhang of Shanghai Jiaotong University has established (Org. Lett. 2007, 9, 5613. DOI: 10.1021/ol702565x)that β-keto…
Several methods have been reported for the stereocontrolled preparation of pyrrolidine and piperidine derivatives. Alison J. Frontier of the University of Rochester has observed (Org. Lett. 2007, 9, 4939.DOI: 10.1021/ol701962w)that…
As alkene metathesis has developed into one of the tools of organic synthesis, many practical questions have arisen. Mc-Val-Cit-PABC-PNP supplier In the course of a synthesis (Org. Lett. 2007, 9,…
Although the enantioselective oxidation of alkyl aryl sulfides is well developed, much less is known about dialkyl sulfides. Tsutomu Katsuki of Kyushu University has designed (J. Am. Chem. Soc. PMID:26446225…
François Morvan of the Université de Montpellier, using the inexpensive dimethyl phosphite, optimized (Tetrahedron Lett. 2008, 49, 3288. DOI: 10.1016/j.tetlet.2008.03.079)the free radical reduction of 1 to 2. BuycataCXium Pd G4…
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