José Barluenga of the Universidad de Oviedo described(Org. Lett. 2008, 10, 4469.DOI: 10.1021/ol801652h)a powerful route from lithiated arenes such as 1 to the benzocyclobutane 3, the immediate precursor to the…
AC5 as a physiological target of HSP21 and describe a molecular mechanism for chloroplast development beneath heat anxiety.Benefits Loss of HSP21 Function Strongly Affects Seedling Improvement under Heat Pressure To…
Ed reagents/materials/analysis tools: RPM PMC. Contributed for the writing in the manuscript: KDR LEC RPM PMC.activation in HBMvECs. (A) Confluent cells have been treated with TNF-a (LHS) or IL-6 (RHS)…
Yujiro Hayashi of Tokyo University of Science and Teruaki Mukaiyama of the Kitasato Institute developed (Chem. Lett. 1220039-63-3 Chemical name 2008, 37, 592 DOI: 10.1246/cl.2008.592) a reduction-oxidation method for converting…
As new drug entities must be usually be prepared as single enantiomers, and as many contain one or more heterocyclic or carbocyclic rings, there is an increased emphasis on the…
Unsaturated half acid esters such as 1 are readily prepared by Stobbe condensation between dialkyl succinate and an aldehyde. Johannes G. de Vries of DSM and Floris P. 1,1-Diethoxy-3-phenylpropan-2-one web…
(+)-6′-Hydroxyarenarol (Anderson) V. T. Perchyonok and Kellie L. Tuck of Monash University found (Tetrahedron Lett. 2008, 49, 4777. DOI: 10.1016/j.tetlet.2008.05.097 ) that a concentrated solution of Bu4NCl and H3PO2 in…
Dactylolide (Jennings), Cytotrienin A (Hayashi), Lepadin B (Charette), Blumiolide C (Altmann) To assemble the framework of the cytotoxic macrolide Amphidinolide X (3), Fèlix Urpí and Jaume Vilarrasa of the Universitat…
F X. Peter Zhang of the University of South Florida extended (Org. PMID:24507727 Lett. 2009, 11, 2273. DOI: 10.1021/ol9005882) Co-catalyzed asymmetric cyclopropanation to the activated ester 2. The product 3…
Enantiomerically-enriched alkoxy stannanes such as 3 are versatile intermediates for synthesis. John R. Falck of UT Southwestern found(Angew. Chem. Int. Ed. 2008, 47, 6586.DOI: 10.1002/anie.200802313)that the simple combination of Bu3SnH…
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