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Total Synthesis of the Galbulimima Alkaloid GB 13

Chemexpress June 11, 2024 0 Comments

Lew Mander of the Australian National University recently reported (J. Am. Chem. PMID:33679749 Soc. 2003, 125, 2400.DOI: 10.1021/ja029725o)the total synthesis of the pentacyclic alkaloid GB 133, which had been isolated…

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Heteroaromatic Construction: The Fukuyama Synthesis of Tryprostatin A

Chemexpress June 11, 2024 0 Comments

Alessandro Palmieri of the University of Camerino developed (Synlett 2010, 2468. DOI: 10.1055/s-0030-1258031) the condensation of a nitro acrylate 1 with a 1,3-dicarbonyl partner 2 to give the furan 3.…

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Functionalization and Homologation of Alkenes

Chemexpress June 11, 2024 0 Comments

Masahito Ochiai developed ( 2008, March 24) the iodosobenzene-mediated cleavage of alkenes to keto aldehydes. PMID:23557924 Thottumkara K. Vinod of Western Illinois University described (Org. Lett. 2010, 12, 5640. DOI:…

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Metal Mediated C-C Ring Construction: The Nevado Route to (-)- Frondosin A

Chemexpress June 11, 2024 0 Comments

Barry M. 6-Bromo-3-chloroisoquinoline structure Trost of Stanford University generated (J. Am. Chem. Soc. 2011, 133, 4766. DOI: 10.1021/ja200971v) a β-keto carbene from the propargyl alcohol 1, leading to the cyclopropane…

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Enantioselective Preparation of Alkylated Stereogenic Centers

Chemexpress June 11, 2024 0 Comments

Jon D. Stewart of the University of Florida established (Chem. Commun. 2010, 46, 8558. DOI: 10.1039/C0CC03119D) a scalable enzymatic reduction of geranial 1 to citronellal 2. Andreas S. Bommarius of…

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C-O Ring Construction: (-)-Sclerophytin A (Morken), (+)-Dictyosphaeric Acid

Chemexpress June 11, 2024 0 Comments

(Taylor), Goniothalesdiol A (Xie/She), (-)-7-Deoxyloganin (Lupton), (-)-Apicularen A (Uenishi)L-783, 277 (Banwell) In the course of a synthesis of (-)-Sclerophytin A (3), James P. Morken of Boston College showed (J. Am.…

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Ts, D. M.; Myagkota, S. V. J. Phys. Chem. Solids 2008, 69, 2520-

Chemexpress June 10, 2024 0 Comments

Ts, D. M.; Myagkota, S. V. J. Phys. Chem. Solids 2008, 69, 2520-2526. (18) Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G. Inorg. Chem. 2013, 52, 9019-9038. (19) Babin,…

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:0 i18:0 18:0 P MUFA 16:1n-7c 17:1n-8ca 18:1n-9c 18:1n-7c

Chemexpress June 10, 2024 0 Comments

:0 i18:0 18:0 P MUFA 16:1n-7c 17:1n-8ca 18:1n-9c 18:1n-7c 20:1n-9c 24:1n-9c P PUFA P n-3 20:5n-3 (EPA) 22:6n-3 (DHA) 22:5n-3 P n-6 20:4n-6 (AA) 22:5n-6 22:4n-6 n-3/n-6 39.1 (0.7) 13.8…

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Substituted Benzenes: The Piers/Lau Synthesis of Hamigeran B

Chemexpress June 10, 2024 0 Comments

Govindasamy Sekar of the Indian Institute of Technology, Madras developed (Chem. Commun. 2011, 47, 5076. DOI: 10.1039/C1CC10568J) an environmentally-friendly procedure for the amination of 1 to 2. Jens-Uwe Peters of…

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Alkene and Alkyne Metathesis: Grandisol (Goess), 8-Epihalosilane (Kouklovsky

Chemexpress June 10, 2024 0 Comments

/Vincent), (+)-Chinensiolide B (Hall) The cost of using Grubbs-type catalysts could be reduced dramatically if the turnover could be improved. PMID:23927631 Richard L. Pederson of Materia, Inc. 1459778-94-9 Chemscene found…

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GjUGT2 amino acid sequence as a query. From an initial list

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Thylsubstituted diyne 6d cyclized with 1hexyne 9a to form a 9:1 mixture

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MCSF Increases Postinduction ON InflammationRodent NAION benefits in ON inflammation in

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G created for use for the treatment of T2DM as

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