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C-H Functionalization: The Davies/Sorensen Synthesis of Aflatoxin B2

Chemexpress March 24, 2024 0 Comments

Shouyun Yu of Nanjing University devised a protocol for the distal dehydrogenation of the acyloxyamide 1 to the alkene 2 (Org. Lett. 2021, 23, 6931. DOI: 10.1021/acs.orglett.1c02509). Armido Studer of…

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N-Heterocycle Construction by Alkene Metathesis

Chemexpress March 24, 2024 0 Comments

The first N-heterocycles prepared by alkene metathesis were simple five- and six-membered ring amides. Ring-closing metathesis of free amines is much more difficult. The diene 1, for instance, gave only…

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Carbon-Carbon Bond Formation: The Fürstner Synthesis of Scabrolide A

Chemexpress March 24, 2024 0 Comments

Yasuharu Yoshimi of the University of Fukui devised a photocatalyst that efficiently promoted the coupling of the acid 1 with acrylonitrile 2, to give, with the net addition of two…

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Functional Group Interconversion: The Minehan Synthesis of Jambolanin C

Chemexpress March 24, 2024 0 Comments

Julian G. 61881-19-4 web West of Rice University used a vitamin B12-based catalyst to prepare the terminal alkene 2 by the elimination of the primary bromide 1 (Chem. PMID:31085260 Sci.…

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Reactions of Alkenes: The Yang Synthesis of Bisdihydrotuberostemonine D

Chemexpress March 24, 2024 0 Comments

Qiang Liu and Yibiao Li of Wuyi University developed a simple protocol for exchanging deuterium into the alkene 1, leading to 2 (Org. Lett. 2021, 23, 7412. DOI: 10.1021/acs.orglett.1c02600). Joseph…

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Alkaloid Synthesis: Aristoquinoline (Reber), Hinckdentine A (Su/Hong), Madangamine E (Hamlin/Dixon), Normacusine B (Xue/Qin), Daphenylline (Lu), Arboridine (Ma)

Chemexpress March 24, 2024 0 Comments

Aristoquinoline (2), isolated from the leaves of the Maqui tree Aristotelia chilensis, was found to be a nicotinic acetylcholine receptor antagonist. BuyMethyl 6-aminopicolinate Buy130473-38-0 Keith P. Reber of Towson University…

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Diels-Alder Cycloaddition: Pepluanol A (Gaich), Trichoderone A (Nay), Davasinol (Ding), Nahuoic Acid A (Alvarez/de Lera), Chloropestolide B (Suzuki), Catharanthine (Dixon)

Chemexpress March 24, 2024 0 Comments

Pepluanol A (3) was isolated from the European milkweed Euphorbia peplus. 957476-07-2 uses BuyLumisterol 3 (>90%) Tanja Gaich of the University of Konstanz devised a route to 3 based on…

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N6 PUFAs in phospholipids (information not shown). Pearson correlation coefficient was

Chemexpress March 23, 2024 0 Comments

N6 PUFAs in phospholipids (data not shown). Pearson correlation coefficient was calculated to assess correlation involving every PUFA. In phospholipids,Kume et al. Nutrition Metabolism 2013, 10:41 http://www.nutritionandmetabolism.com/content/10/1/Page 4 ofTable 1…

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9111)) in staining medium (SM: clear MEM with supplements, 1 MEM (Invitrogen 51200), ten mM

Chemexpress March 23, 2024 0 Comments

9111)) in staining medium (SM: clear MEM with supplements, 1 MEM (Invitrogen 51200), 10 mM Hepes (Invitrogen 15630), 1 GlutaMAX1 (Invitrogen 35050)) for 45 min. Cells were washed 4 times…

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Oxidation: The Zhu Synthesis of Cepharamine

Chemexpress March 23, 2024 0 Comments

Oleg V. Larionov of the University of Texas at San Antonio used an acridine photocatalyst to mediate the decarboxylative conversion of the carboxylic acid 1 to the sulfonamide 2 (Chem.…

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D GFR applying FITCinulin clearance as a a lot more direct measure of

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Edict roughly equal distribution of spins on each on the P

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2 Hz, 1H), two.41-2.63 (m, 3H), 1.27-1.63 (m, 2H), 1.12 (s, 3H), 1.00-

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Ventilator time with full cuff inflation completed the test with a

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