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Enantioselective Preparation of Alkylated Stereogenic Centers

Chemexpress June 11, 2024 0 Comments

Jon D. Stewart of the University of Florida established (Chem. Commun. 2010, 46, 8558. DOI: 10.1039/C0CC03119D) a scalable enzymatic reduction of geranial 1 to citronellal 2. Andreas S. Bommarius of…

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C-O Ring Construction: (-)-Sclerophytin A (Morken), (+)-Dictyosphaeric Acid

Chemexpress June 11, 2024 0 Comments

(Taylor), Goniothalesdiol A (Xie/She), (-)-7-Deoxyloganin (Lupton), (-)-Apicularen A (Uenishi)L-783, 277 (Banwell) In the course of a synthesis of (-)-Sclerophytin A (3), James P. Morken of Boston College showed (J. Am.…

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Ts, D. M.; Myagkota, S. V. J. Phys. Chem. Solids 2008, 69, 2520-

Chemexpress June 10, 2024 0 Comments

Ts, D. M.; Myagkota, S. V. J. Phys. Chem. Solids 2008, 69, 2520-2526. (18) Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G. Inorg. Chem. 2013, 52, 9019-9038. (19) Babin,…

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:0 i18:0 18:0 P MUFA 16:1n-7c 17:1n-8ca 18:1n-9c 18:1n-7c

Chemexpress June 10, 2024 0 Comments

:0 i18:0 18:0 P MUFA 16:1n-7c 17:1n-8ca 18:1n-9c 18:1n-7c 20:1n-9c 24:1n-9c P PUFA P n-3 20:5n-3 (EPA) 22:6n-3 (DHA) 22:5n-3 P n-6 20:4n-6 (AA) 22:5n-6 22:4n-6 n-3/n-6 39.1 (0.7) 13.8…

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Substituted Benzenes: The Piers/Lau Synthesis of Hamigeran B

Chemexpress June 10, 2024 0 Comments

Govindasamy Sekar of the Indian Institute of Technology, Madras developed (Chem. Commun. 2011, 47, 5076. DOI: 10.1039/C1CC10568J) an environmentally-friendly procedure for the amination of 1 to 2. Jens-Uwe Peters of…

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Alkene and Alkyne Metathesis: Grandisol (Goess), 8-Epihalosilane (Kouklovsky

Chemexpress June 10, 2024 0 Comments

/Vincent), (+)-Chinensiolide B (Hall) The cost of using Grubbs-type catalysts could be reduced dramatically if the turnover could be improved. PMID:23927631 Richard L. Pederson of Materia, Inc. 1459778-94-9 Chemscene found…

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Advances in Organic Functional Group Transformation

Chemexpress June 10, 2024 0 Comments

There have been several significant advances in N-alkylation using alcohols. Matthias Beller of Universität Rostock devised (Angew. PMID:24202965 Chem. Int. Ed. 2010, 49, 8126. DOI: 10.1002/anie.201002576) a Ru catalyst for…

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Organocatalysis of Carbocyclic Construction: The MacMillan Synthesis of (+)-Frondosin

Chemexpress June 10, 2024 0 Comments

B One of the more powerful applications of organocatalysis has been the enantioselective transformation of preformed prochiral rings. In the five-membered ring series, Nobuyuki Mase of Shizuoka University effected (Synlett…

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Organic Functional Group Protection and Deprotection

Chemexpress June 10, 2024 0 Comments

Corey R. J. Stephenson of Boston University devised (Chem. Commun. 2011, 47, 5040. DOI: 10.1039/C1CC10827A) a protocol using visible light for removing the PMB group from 1 to give 2.…

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Reactions of Alkenes

Chemexpress June 10, 2024 0 Comments

Ana C. Fernandes of the Instituto Superior Técnico, Lisboa, devised (Tetrahedron Lett. 2010, 51, 1048. DOI: 10.1016/j.tetlet.2009.12.061) an effective Re catalyst for the solvent-free hydrogenation of an alkene 1. Yasushi…

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2-Bromo-3,4,6-trifluorophenylisothiocyanate

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2-Biphenylcarboxaldehyde (CAS 1203-68-5)

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2-(benzylamino)propanoic acid hydrochloride

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2-[Benzyl-(2-chloro-acetyl)-amino]-4-methyl-thiazole-5-carboxylic acid ethyl ester

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