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Arrays of Sterogenic Centers: The Inoue Synthesis of Hikizimycin

Chemexpress March 15, 2024 0 Comments

Chi-Ming Che of the University of Hong Kong designed an Fe catalyst that mediated the enantioselective dihydroxylation of the unsaturated ester 1, delivering the diol 2 (Angew. Chem. Int. 87789-35-3…

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C-C Bond Formation: The Chen/Yang Synthesis of Spirochensilide A

Chemexpress March 15, 2024 0 Comments

Patrick J. Walsh of the University of Pennsylvania and Jianyou Mao of Nanjing Tech University assembled the carboxylic acid 3 by the decarboxylative coupling of glutaric anhydride 2 with the…

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Reactions of Alkenes: The Park Synthesis of Nitramine

Chemexpress March 15, 2024 0 Comments

Gong-Qing Liu and Yong Ling of Nantong University prepared the selenyl alcohol 2 by the oxidative addition of diphenyl diselenide to the alkene 1 (J. Org. PMID:24580853 Chem. 2021, 86,…

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Essed; E mail: [email protected]; Tel.: 6096684961; Fax: 6096684949. Received: 17 June 2013; in

Chemexpress March 14, 2024 0 Comments

Essed; E-mail: [email protected]; Tel.: 6096684961; Fax: 6096684949. Received: 17 June 2013; in revised kind: 14 August 2013 / Accepted: 23 August 2013 / Published: 20 SeptemberAbstract: The objective of this…

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Ational pharmaceutical companies to style and manufacture novel carbohydratebased drugs. While

Chemexpress March 14, 2024 0 Comments

Ational pharmaceutical companies to design and style and manufacture novel carbohydratebased drugs. Even though a number of glycans have therapeutic properties these of marine origin possess a unique position. This…

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“CuH in a Bottle” for Asymmetric Hydrosilylations

Chemexpress March 14, 2024 0 Comments

Bruce H. PMID:24278086 Lipshutz and Bryan A. Frieman from the University of California, Santa Barbara, have made investigations on as a hydrosilylation reagent regarding stability and preparation (Angew. 1450752-97-2 Formula…

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Oxidation: The Sherman/Williams Synthesis of Baulamycin A

Chemexpress March 14, 2024 0 Comments

Zhankui Sun of Shanghai Jiao Tong University devised photolytic conditions for the oxidation of the acid 1 to the alcohol 2 (J. Org. Chem. 2020, 85, 5019. DOI: 10.1021/acs.joc.0c00312). Kazunori…

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Reactions of Alkenes: The Ogura Synthesis of Celafolin B-3

Chemexpress March 14, 2024 0 Comments

Hisao Yoshida of Kyoto University developed conditions for the direct hydroamination of the alkene 1 to the primary amine 2 (J. Am. Chem. Soc. 2020, 142, 12708. DOI: 10.1021/jacs.0c04598). Wei…

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Diels-Alder Cycloaddition: 4β-Acetoxyprobotryane-9β,15α-diol (Li), Penostatin C (Tong), Sucutinirane C (Pitsinos), Glaucocalyxin A (Jia), PF-1018 (Trauner), Abyssomycin C (Vidali)

Chemexpress March 14, 2024 0 Comments

4β-Acetoxyprobotryane-9β,15α-diol (3) was isolated from the wine grape necrotrophic fungus Botrytis cinerea. En route to 3, Chuang-Chuang Li of the Southern University of Science and Technology optimized the Rh-catalyzed cycloaddition…

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C-H Functionalization: The Harusawa Synthesis of Trichodenone C

Chemexpress March 14, 2024 0 Comments

Lutz Ackermann of the Georg-August-Universität Göttingen effected azidation of 1 selectively at the methine distal to the electron-withdrawing ester, leading to 2 (Chem. Sci. 2021, 12, 2890. DOI: 10.1039/D0SC05924B). Li-Zhu…

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  • 48 decrease than those perfused with BAY 412272 alone (11.15 0.91 vs. 17.76 1.87 fmol/mg tissue
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D by scaling is closer to the observed rate at 10 C

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C experiments to mimic diagenesis at burial temperature. The outcomes highlighted

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Hed an in vitro assay in which intestinal epithelial cells were

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48 decrease than those perfused with BAY 412272 alone (11.15 0.91 vs. 17.76 1.87 fmol/mg tissue

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