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Allylation of Aldehydes with Allylstannane

Chemexpress April 28, 2024 0 Comments

Thierry Ollevier and Zhiya Li from Université Laval, Quebec, have reported on the bismuth-catalyzedSakurai reaction toward the synthesis of homoallylic alcohols (Eur. J. 1505818-73-4 web Org. Chem. 1246761-84-1 supplier 2007,…

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Rhodium-Catalyzed Conjugate Addition-Enantioselective Protonation

Chemexpress April 28, 2024 0 Comments

The asymmetric synthesis of α,α’-dibenzyl esters 1 from α-benzyl acrylates and diversely substituted boronic acids was performed by Christopher Frost and co-workers from University of Bath (Org. 1345728-51-9 Formula Lett.…

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Synthesis of Peptidomimetics via Cross-Metathesis

Chemexpress April 28, 2024 0 Comments

Stephen Caddick and co-workers from University College London were successful in the generation of peptidomimetics via stereoselectivecross-metathesis (Org. Biomol. Chem. Formula of 37342-97-5 2007, 5, ASAP.DOI: 10.1039/b700804j). By applying Grubbs’…

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G option; T2 time point at which the maximum alter of

Chemexpress April 27, 2024 0 Comments

G resolution; T2 time point at which the maximum transform of F340/F380 was reached soon after the substitution of the SBS with the NH4Cl bathing remedy; T3 time point (at…

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By about 1.5 whereas for homooligomeric BAX the improvement is about 4 Moreover

Chemexpress April 27, 2024 0 Comments

By about 1.5 whereas for homooligomeric BAX the improvement is about four Additionally, making use of of SDSL-EPR distance data mitigates theJ Struct Biol. Author manuscript; obtainable in PMC 2017…

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Solvent-Free [3+2] Cycloadditions

Chemexpress April 27, 2024 0 Comments

The groups of Fernando Cossio from Universidad del País Vasco-Euskal Herriko Unibertsitatea and Angel Díaz-Ortiz from Universidad de Castilla-La Mancha, Spain, have made investigations toward the stereochemical outcome for the…

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Synthesis of Thiosugar-Annulated Dihydropyrimidines

Chemexpress April 27, 2024 0 Comments

The group of Lal Dhar Yadav from the University of Allahabad, India, has reported on a Biginelli-type reaction of unprotected aldoses, 2-methyl-2-phenyl-1,3-oxathiolan-5-one 1 as CH-acidic building block and urea/thiourea under…

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Hydrozirconation-Transmetalation-Aldimine Addition Sequence

Chemexpress April 27, 2024 0 Comments

Hydrozirconation is a mild method for the selective preparation of functionalized organometallics and its compatibility with a range of common protecting groups represents a considerable advantage of these species over…

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Oxidative Dearomatization/Transannular Diels-Alder Cascade

Chemexpress April 27, 2024 0 Comments

The group of Samuel Danishefsky from Columbia University has reported on an oxidative dearomatization/transannular Diels-Alder sequence as key step in the total synthesis of (±)-11-O-debenzoyltashironin (4) (J. Am. Chem. Soc.…

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New Catalysts and Strategies for Alkene and Alkyne Metathesis

Chemexpress April 27, 2024 0 Comments

Diastereoselectivity in ring-closing metathesis can be achieved under either kinetic or thermodynamic control. PMID:23539298 Siegfried Blechert of the Technische Universität Berlin has found (Angew. Chem. Int. Ed. 2006, 45, 1302.…

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